Sky Movies subscribers are now able to watch every Bond film in full, uninterrupted, in high definition.
Earlier this year, the broadband, phone and subscription TV provider secured the exclusive rights to the 22 films in the 007 series from rival broadcaster ITV.
It is 50 years since the original James Bond film - 'Dr No' starring Sean Connery - hit the silver screen, and Sky is marking this landmark with a dedicated channel throughout October.
Viewers will also be able to watch the series on-demand using the Sky Anytime+ and Sky Go services.
Ian Lewis, Director of Sky Movies, said his firm had been "simply delighted" to secure the Bond films for its TV subscribers.
"Everything about these films is iconic - whether it's the cars, the gadgets or the catchphrases. What's more, they've become hugely significant culturally, demonstrating the best of British film," he stated.
"It's an honour for us to have all of them for our customers, and we will ensure that we do them justice across Sky Movies, giving our customers the best possible experience in watching them."
The 23rd film in the popular franchise - 'Skyfall' - is released next week, marking Daniel Craig's third outing as the British Secret Service agent.